Scarlett Johansson Natasha Romanoff / Black Widow
Chris Evans Steve Rogers / Captain America
Hayley Atwell Peggy Carter
Elizabeth Olsen Wanda Maximoff / Scarlet Witch (uncredited)
Samuel L. Jackson Nick Fury
Sebastian Stan Bucky Barnes / Winter Soldier
Frank Grillo Brock Rumlow
Aaron Taylor-Johnson Pietro Maximoff / Quicksilver (uncredited)
Emily VanCamp Kate / Agent 13
Jenny Agutter Councilwoman Hawley
Anthony Mackie Sam Wilson / Falcon
Robert Redford Alexander Pierce
Stan Lee Executive Producer, Thanks, Smithsonian Guard
Cobie Smulders Maria Hill
Toby Jones Dr. Arnim Zola
Thomas Kretschmann Baron Wolfgang von Strucker (uncredited)
Brian Michael Bendis Thanks
Gary Sinise The Smithsonian Narrator (voice)
Pat Healy Scientist #1
Anthony Russo Director
Branka Katić Renata
Stephen McFeely SHIELD Interrogator #2, Screenplay
Chin Han Councilman Yen
Callan Mulvey Jack Rollins
Alan Dale Councilman Rockwell
Maximiliano Hernández Jasper Sitwell
Sam Hargrave Stunt Double
Joe Russo Dr. Fine, Director
Steven Culp Scudder
Henry Kingi Stunt Double
Danny Pudi Com Tech #1
Henry Goodman Dr. List (uncredited)
Joss Whedon Man on Escalator in Museum (uncredited)
Louis D'Esposito Executive Producer
Kevin Feige Producer
Eddie J. Fernandez Strike Agent
Amy Johnston Stunt Double
Nestor Serrano Committee General (uncredited)
Jack Kirby Comic Book
Dominic Rains CIA Instructor
Andy Park Conceptual Illustrator
Bernard White Councilman Singh
Abigail Marlowe SHIELD Tech
Adetokumboh M'Cormack French Radio Pirate
D.C. Pierson Apple Employee
Joe Simon Comic Book
Christopher Markus SHIELD Interrogator #1, Screenplay
Salvator Xuereb French Pirate #1
Heidi Moneymaker Stunt Double
Aaron Himelstein Launch Tech #1
Garry Shandling Senator Stern
Rob Mars Utility Stunts
Evan Parke SHIELD Agent
Don Heck Thanks
Fernando Chien Utility Stunts
Georges St-Pierre Georges Batroc
Jeffrey Ford Editor
Robert Clotworthy Fury Car Voice (voice)
Adam N. White Camera Operator
Philip J. Silvera Utility Stunts
Gene Colan Thanks
Frédéric North Pilot
Ethan Rains Lead EMT
Tim Sitarz Utility Stunts
Chris Brewster Stunt Double
Annie Ellis Utility Stunts
Chris Durand Utility Stunts
Alan Fine Executive Producer
Shauna Duggins Stunt Double
Jon H. Epstein Utility Stunts
Jon Sklaroff Charlie XO
Mitchell Bell Associate Producer